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jayscheuerle
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Re: What drives an atom? new [Re: Pess]
      #2520725 - 07/15/08 03:32 PM

Late to this...

Would it make sense to think of an electron as a layer of atmosphere around the nucleus with additional electrons simply increasing the density?

--------------------
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Dane B
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Re: What drives an atom? new [Re: Pess]
      #2521802 - 07/16/08 06:05 AM

Michael:

(my name is Dane by the way)

I see your point - if a photon is absorbed by an electron and that electron then emits another photon, that new photon does not carry information about the original position of the electron.

Perhaps I have misinterpreted my professor when studying this aspect of quantum mechanics, but I was given the impression that the position of electrons in orbitals could be located, and that when this was done repeatedly it formed the shape of the orbital in which the electron was originally located.

If this is not the case, and the position of an electron within an orbital cannot be located, I would appreciate a link so I can confirm this and learn more about it.

In the experiment UWastronomer mentioned it appears the experimenters believe it may be possible to locate an electron within an orbital. How do you reconcile this with your claim?

(oh, and UWastronomer, if you could give a link for us to read more about this experiment it would be appreciated!)

--------------------
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Pess
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Re: What drives an atom? new [Re: jayscheuerle]
      #2522143 - 07/16/08 10:39 AM

Quote:

Late to this...

Would it make sense to think of an electron as a layer of atmosphere around the nucleus with additional electrons simply increasing the density?




Close....

Better to think of the electrons location as a 'probability cloud'.

..and here is where it gets counterintuitive....the absolute position of the electron is not set until it is observed. Therefore the electron can be observed on either side of a barrier.

The electron is not racing around the nucleus like a race car around a track...it exists as a 'smear' around the nucleus which only resolves to a point when an outside observation is made.

I hope this analogy is clear because it has some profound implications.

Another analogy -- let us say I exist as a probability smear. MY exact location is not determined until you come look for me.

Now lets say you build a jail cell that encompasses 50% of the 'smear area'.

You periodically come look for me to verify my location.

Sometimes you'll find me safely locked in the cell, other times you'll find me outside the locked door.

<shrugs>

Pesse (Hope the 'jail' analogy doesn't give you guys any ideas..) Mist

--------------------
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HiggsBoson
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Re: What drives an atom? new [Re: Dane B]
      #2523545 - 07/16/08 11:56 PM

Quote:

Michael:

(my name is Dane by the way)

I see your point - if a photon is absorbed by an electron and that electron then emits another photon, that new photon does not carry information about the original position of the electron.

Perhaps I have misinterpreted my professor when studying this aspect of quantum mechanics, but I was given the impression that the position of electrons in orbitals could be located, and that when this was done repeatedly it formed the shape of the orbital in which the electron was originally located.

If this is not the case, and the position of an electron within an orbital cannot be located, I would appreciate a link so I can confirm this and learn more about it.

In the experiment UWastronomer mentioned it appears the experimenters believe it may be possible to locate an electron within an orbital. How do you reconcile this with your claim?

(oh, and UWastronomer, if you could give a link for us to read more about this experiment it would be appreciated!)




Hello Dane

Somewhere at the beginning of this thread I indicated that I would rather believe that I do not understand the experiment than to suggest that they do not know they are doing.

I use the ground state of the electron in Hydrogen because it the only case where I have personally done the math. The higher states are the familiar ones taught to you in chemistry. Each of these possible energy states are allowed. Also super positions of these states are allowed. The energy states that look like particles are those that are made up of these combined states. In these high states we can locate an electron limited by the uncertainty principle. It may be the case that this is the type of state that they seek. This would be as meaningful as asking the position of a free electron in a metal. It can go where it will. One can talk about its position because if its complex high energy wave function.

You did not misunderstand your professor. I was taught the same thing when I was in high school. This is called the classical view of the atom and the electron. We now know that it is useful but not correct. Unfortunately unless one wants to confront Quantum, it is the best picture available.

You are correct. If you wish to know where in the orbit the ground state electron is located you will be disappointed. If your photon hits the electron and knocks it into a new higher energy orbit, there is no chance of getting a location from the photon that will be emitted when the electron drops back to the ground state.

--------------------
Michael

ATM: 6" F/9 Newtonian Travel Scope
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Taqyon
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Re: What drives an atom? new [Re: HiggsBoson]
      #2523902 - 07/17/08 07:10 AM

Quote:

Why would we doubt the existence of the photon? We see!


I say we see because sensors in our eyes can detect the wave energy and not because a piece of matter (photon) physically travels all the way to hit our iris.

I suppose the old particle vs wave attributes. What proof is there for the particle / photon?

Unless I'm completely misunderstanding the definition of a photon - perhaps its only meant to describe the energy in a given section of the wave?

--------------------
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Taqyon
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Re: What drives an atom? new [Re: Pess]
      #2523907 - 07/17/08 07:14 AM

How would one test to find the location of an electron in the atom?

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HiggsBoson
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Re: What drives an atom? new [Re: Taqyon]
      #2524211 - 07/17/08 11:04 AM

Tagyon

There are a number of concepts in play in your question. When I suggest that photons exist I do not mean to imply that they are little balls of stuff. They are mass-less quanta of electromagnetic radiation. From a physical prospective the word exist does not imply mass.

A particle in physics need not have mass. The standard model of particle physics speaks of force mediating particles. The photon and gluon are examples of mass-less particles.

Be aware that the word particle in physics does not imply a small ball of stuff. It is jargon. The word is used for historical reasons. It is hard to change and I am unaware of a better word. All particles are modeled as wave functions in physics.

http://en.wikipedia.org/wiki/Standard_model

Both the electron and photons can exhibit properties that we associate with classical particles. 100 years ago the phrase particle wave duality was used to refer to this discussion about this fact. Quantum Mechanics resolved this issue. Other than to marvel at the profoundness of this it is not a mystery today. The behavior is completely predictable.

Simple electrons in low energy states are not little balls. In the ground state of hydrogen to ask where the little ball is in its orbit is to misunderstand the electron. The electron wave function is spherically symmetrical about the nucleus. That is our best knowledge as to its location.

The wave function for the ground state of the electron in hydrogen is proportional to R time e^-R which is zero at the origin and not zero elsewhere. It is symmetrical about the nucleus (origin ). This model is all we know about the electron’s location. There is no little ball and no location within an orbit. It is possible to create high energy electrons whose behavior is similar to a small ball of negatively charged stuff. An electron in a beam in the back of a TV tube would be an example. ( Soon I will have to find a new example since the tube type displays are fast becoming a thing of the past ). Many lab experiments that deal with slits and diffraction patterns deal with such high energy electrons.

The loss of the ability to determine the absolute location of things was very disturbing to Einstein and he ultimately rejected this view. While he helped develop quantum and understood it. He did not agree that it was the ultimate description of nature. He was not able to find a deeper view and to date the problem has not been solved. Of course to say it has not been solved is to presuppose that a solution exist which may not be the case.

--------------------
Michael

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Taqyon
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Re: What drives an atom? new [Re: HiggsBoson]
      #2524246 - 07/17/08 11:19 AM

Thank you Michael

I'm getting more interested as this thread continues.

Just to get back to my original question. Using an example used earlier, if a bar is inserted through the middle of an atom, and kept there, would sampling the location of the electron produce 50/50 results of it being on either side? I other words, there is no way to "trap" it on one side (the tunneling thing)?

So, if an electron has mass and it's "moving" about in this manner - it seems as if it's appearing and dissapearing in and out of existance at different locations, or tunneling through whatever you present in its way, is there still no energy consuption?

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llanitedaveModerator
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Re: What drives an atom? new [Re: HiggsBoson]
      #2524672 - 07/17/08 02:58 PM

Quote:

Of course to say it has not been solved is to presuppose that a solution exist which may not be the case.




However incomprehensible such a solution may be, to propose that there IS no solution is even more incomprehensible. That would imply an irresolvable gap between the micro and macro worlds, a "two-worlds" hypothesis with no connection between them.

Finding a unity between relativity and quantum theory has been the biggest challenge in physics of our time. There are plenty of plausible potential solutions available -- simply no way at present to decide between them. I'm hoping that some experiment eventually becomes available that will start to weed out the unification candidates.

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Pess
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Re: What drives an atom? new [Re: Taqyon]
      #2524944 - 07/17/08 05:39 PM

Quote:

So, if an electron has mass and it's "moving" about in this manner - it seems as if it's appearing and dissapearing in and out of existance at different locations, or tunneling through whatever you present in its way, is there still no energy consuption?




"tunneling' is really a bad descriptive term.

It implies the electron somehow travels through whatever barrier put in its way, Like a car barreling through a flaming haystack.

That is a wrong analogy.

Most would say the electron doesn't exist as a discrete object until someone attempts to measure some characteristic of it.

Before being measured it is only a probability cloud that is encompassing the entire universe. Of course detecting an electron from an atom in your heart muscle out near the orbit of Pluto is near nil. But near nil is not the same as zero.

The probability approaches 1 when you get to the appropriate orbital around the electrons nucleus.

This probability cloud is said to collapse into a discrete particle when that particle is observed.

Since. all other things being equal, there is a 50/50 chance that if you put a barrier up directly across the nucleus-- the electron stands a chance of detection on either side of the barrier when the probability cloud collapses.

Another related concept is entanglement. Which Einstein referred to as "spooky action at a distance'. Here we have two entangled particles that go their separate ways yet collapse of one particles probability cloud (by measuring it) somehow instantaneously influences how its separated partners probability cloud will collapse.

Pesse (You are now entering the Twilight Zone) Mist

--------------------
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Dane B
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Re: What drives an atom? new [Re: HiggsBoson]
      #2525062 - 07/17/08 06:50 PM

Quote:

I use the ground state of the electron in Hydrogen because it the only case where I have personally done the math. The higher states are the familiar ones taught to you in chemistry. Each of these possible energy states are allowed. Also super positions of these states are allowed. The energy states that look like particles are those that are made up of these combined states. In these high states we can locate an electron limited by the uncertainty principle. It may be the case that this is the type of state that they seek.




Michael - I don't understand why you suggest electrons in higher energy orbitals can be located, but not in a 1s/ground state orbital.

--------------------
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HiggsBoson
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Re: What drives an atom? new [Re: Taqyon]
      #2525461 - 07/17/08 10:04 PM

Quote:

Thank you Michael

I'm getting more interested as this thread continues.

Just to get back to my original question. Using an example used earlier, if a bar is inserted through the middle of an atom, and kept there, would sampling the location of the electron produce 50/50 results of it being on either side? I other words, there is no way to "trap" it on one side (the tunneling thing)?

So, if an electron has mass and it's "moving" about in this manner - it seems as if it's appearing and dissapearing in and out of existance at different locations, or tunneling through whatever you present in its way, is there still no energy consuption?




Tagyon

Thank you for asking questions that push me to rethink my positions. If only I could derive my income from researching and responding to questions on this forum. Currently I must work this stuff in when I can.

The question of adding a 'bar' to the hydrogen atom. I interpret your 'bar' to be a plane that bisects the atom. The question then being to determine which side contains the electron at any given moment. Clearly if the plane is imaginary the problem has not changed at all. The electron is symmetrically distributed about the nucleus. This is all one can know.

If one says that the plane is made of some new material that is thin in comparison to the size of the proton. ( If I knew of such a material I would not be sitting here typing.) This material would be modeled as a potential field in the Schrodinger equation along with the electric field provided by the proton. This would give rise to a different solution for the electron which, by my speculation only, would not be spherically symmetrical. This new solution would allow you to determine the probability of observing the electron on either side of the barrier and allow you to determine how often it will tunnel to the other side(1)(2).

Your second question still clings to the notion that the electron is moving. In the ground state motion relative to the nucleus is not required. Your question as to where the energy is coming from is an insightful one. I have pondered this one for many years. I look at refrigerator magnets and ask the same question. I look at taking one's finger and touching the table. The table is willing to push against the finger for as long as you are willing to push. Where does the energy come from? A photon crosses the void between galaxies with no regard for how long it will take and never gets tired! What gives?

At this point I am not willing to even speculate on such questions.

Dave

Many years ago I had fantasies about being one of the guys who would lead the charge to find unification. Now I just sit on the side lines cheering them on. One of my goals for retirement is to refresh my math skills to the point that I can just understand what they are talking about.

1) The ammonia is a well know example of quantum tunneling. It has three Hydrogen atoms attached to a Nitrogen. The three form a tetrahedron with the N atom sticking out on one side. The N atom actually tunnels through the potentials of the three Hydrogen to stick out the other side several times per second.

2) Increasing the mass of the particle will exponentially reduce the probability of tunneling. An electron is more likely to tunnel through something than a person.

Increasing the energy of the barrier will exponentially reduce the probability of tunneling. You are more likely to tunnel through a paper wall than a fire door.


Increasing the width of the barrier will exponentially reduce the probability of tunneling. You are more likely to tunnel through your front door than through a mountain.

--------------------
Michael

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HiggsBoson
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Re: What drives an atom? new [Re: Dane B]
      #2525482 - 07/17/08 10:13 PM

Quote:

Michael - I don't understand why you suggest electrons in higher energy orbitals can be located, but not in a 1s/ground state orbital.




Each energy state has a specific amount of energy. Imagine all of those orbitals from chemistry. Each represents a different energy state for the electron. It is possible to find solutions for the electron that consist of 20% one state and 80% some other state. Combinations are allowed states. Clearly one can create states with high probabilities in one location and very low probabilities in other locations. The more states that are combined the greater the freedom to 'place' the electron where you wish. In the extreme case the electron is free to move anywhere such as inside of a metal. The outer electrons are not attached to their atoms. They float in a sea of electrons. These are the ones that make electrical current flow possible. Place a charge at one end and all of the electrons shift.

The math here is very similar to that used by audio engineers to create desired musical waveforms using only sine waves of different frequencies and amplitudes. This kind of wave form construction is rather common in electrical engineering. It is not the same. I only assert that the mathematical concepts are similar.

If you think about it if an electron is traveling across the room we consider it localized if we know its position within one millimeter. On the other hand asking which side of the nucleus it is on is demanding much greater precision. Most macro experiments are in fact on such a large scale that it is easy to ignore the uncertainty of position. If it hits my CCD imaging sensor I will say that I got it to within a few microns. But that is no where near the Heisenberg limit. Asking which side of the nucleus is inside of that limit*.

* I did not calculate it but I seem to remember it is true. If I delve into a little used cobweb filled part of my brain it may be the case that one can compute the radius at which the probability of observation is 50%. This should be the classical electron radius. This would be the uncertainty of position for the case of 50% chance of observation. This is a very small area compared to the size of a pixel in an image sensor. If that pixel comes on, I only know its position to within the size of the pixel. The smallest of the Astro cameras that I have seen would make this around 7 microns. There are a lot of atoms in 7 microns.

--------------------
Michael

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Joad
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Re: What drives an atom? new [Re: llanitedave]
      #2525611 - 07/17/08 11:28 PM

Quote:

Quote:

Of course to say it has not been solved is to presuppose that a solution exist which may not be the case.




However incomprehensible such a solution may be, to propose that there IS no solution is even more incomprehensible. That would imply an irresolvable gap between the micro and macro worlds, a "two-worlds" hypothesis with no connection between them.

Finding a unity between relativity and quantum theory has been the biggest challenge in physics of our time. There are plenty of plausible potential solutions available -- simply no way at present to decide between them. I'm hoping that some experiment eventually becomes available that will start to weed out the unification candidates.




Please, anyone correct me if I am getting any point of this wrong. So here goes:

My basic understanding is that, due to the conditions that are well known under the interpretation of the Heisenberg Uncertainty Principle, or the Bohr's Copenhagen Interpretation, the position of an electron cannot be measured or observed because the measuring or observing instrument gets in the way (as has been so well described in this thread by the explanations of what happens when an "observing" photon bumps an electron into a higher energy state).

But while the electron cannot be located with certainty, its orbital status can be approximated through wave equations (most famously the Schroedinger Wave Equations). These equations, which are mathematically produced, create a "picture" not of the electron's postion but of the highest mathematical density/approximation of where it could be.

Thus, in a sense, we are never observing an electron at all, only our mathematical calculations. In other words, our "language" (in this case, the symbolic language of mathematics), always gets in the way, or "mediates" between us and reality.

This is why one of the philosophical conclusions of the Uncertainty Principle is that reality has "evaporated," or vanished (this is a very popular notion in philosophy and the Humanities, and is the basis of one of the most famous theories of postmodernity).

Now, I am not sympathetic with the postmodern "evaporation" interpretation, but it does place one heck of a barrier in the way of a solution so long as we are looking to the scientific method of prediction and observation (that is, if our "pictures" are really only pictures of our own calculations and not of an extra-mathematical reality). This is probably why string theory is still so disappointing: it is elegant language but non-observable.

So far. I'm not ruling anything out.


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HiggsBoson
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Re: What drives an atom? new [Re: Joad]
      #2525719 - 07/18/08 12:43 AM

Joad

It is way past my bed time but I will try to respond using the few brain cells that are still firing.

Quote:

My basic understanding is that, due to the conditions that are well known under the interpretation of the Heisenberg Uncertainty Principle, or the Bohr's Copenhagen Interpretation, the position of an electron cannot be measured or observed because the measuring or observing instrument gets in the way (as has been so well described in this thread by the explanations of what happens when an "observing" photon bumps an electron into a higher energy state).




The problem of the measurement equipment getting in the way is called the general measurement problem. I observe this problem when I do documentary film making. People are different when I turn on the camera. Thus, it is impossible for me to document what they would do if the camera were not present. The measurement problem is different from the uncertainty principle. The uncertainty principle says even with perfect equipment and execution there is a limit to what is knowable about things in the quantum realm. The principle quantifies this limit mathematically such that it is predictable. This limit assumes no measurement error and plays a role in physics similar to diffraction. With perfect optics the diffraction limit remains.

Quote:

But while the electron cannot be located with certainty, its orbital status can be approximated through wave equations (most famously the Schroedinger Wave Equations). These equations, which are mathematically produced, create a "picture" not of the electron's position but of the highest mathematical density/approximation of where it could be.




Short answer: Yes! The wave function produces a specific prediction of observation. The predictions contain uncertainty but have been accurate to the limits of our ability to test. While the limits are depressing, our ability to predict the uncertainty is comforting.

Quote:

Thus, in a sense, we are never observing an electron at all, only our mathematical calculations. In other words, our "language" (in this case, the symbolic language of mathematics), always gets in the way, or "mediates" between us and reality.




The observation consumes the electron. What ever you learn from the observation, the electron you observed is gone. There is no way to observe it without distorting its behavior.

Quote:

This is why one of the philosophical conclusions of the Uncertainty Principle is that reality has "evaporated," or vanished (this is a very popular notion in philosophy and the Humanities, and is the basis of one of the most famous theories of postmodernity).




This was Einstein’s problem. Today it is accepted by most that nature is not constrained to be the way that makes since to us. Nowhere are we promised that electrons have knowable positions. What electrons do is reality. What we perceive is the illusion. We perceive that objects have color. This is an illusion. The colors we see exist only in the human mind. We apply color to a very narrow range of electromagnetic radiation. These photons are not special in any way other than to us.

Quote:

Now, I am not sympathetic with the postmodern "evaporation" interpretation, but it does place one heck of a barrier in the way of a solution so long as we are looking to the scientific method of prediction and observation (that is, if our "pictures" are really only pictures of our own calculations and not of an extra-mathematical reality). This is probably why string theory is still so disappointing: it is elegant language but non-observable




I am an instrumentalist. This means that the models are useful for their predictive value but need not be the most accurate description of nature. The Determinist view the equations as an accurate description of nature. Determinist suffer many disappointments when a well believed theory is shown to be inaccurate. Instrumentalist simply value the old one, usually because it is simpler and value the new one because it works over a wider range of cases.

I come from the camp that feels that all models are wrong but some are useful.

--------------------
Michael

ATM: 6" F/9 Newtonian Travel Scope
ATM: 12.5" F/4.5 Real Soon Now...


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Taqyon
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Re: What drives an atom? new [Re: HiggsBoson]
      #2526005 - 07/18/08 07:43 AM

I appreciate the time you put in to (try to) get me in the right line of tought.

Quote:

If I knew of such a material I would not be sitting here typing.



You can try my bank balance? Seriously, what I'm after is weather there is really tunneling taking place, or it's just a question of where the electron is at any given time. Will it be possible to trap an electron on one side? Or will it ignore the barrier and pop to the other side.

Quote:

A photon crosses the void between galaxies with no regard for how long it will take and never gets tired! What gives?


Hang on - you said that a photon is just a measurement of a quanta of light, not necessarliy a physical thing (hence 0 mass). A wave on the other hand will continue forever in the fabric of space unless affected by other waves of the same frequency.

But wait - if a black hole swallows light, it means its eating up the space fabric that carries the waves. Wow I love this.

--------------------
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HiggsBoson
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Re: What drives an atom? new [Re: Taqyon]
      #2526319 - 07/18/08 11:20 AM

The electron in the Hydrogen atom is a function of the potential created by the proton. In the simplest case there is only one atom in the universe with one proton and one electron. This electron is symmetrically distributed about the nucleus. If the barrier is real the solution is different. I do not know what it looks like and will not speculate. ( I have a guess but I have not looked at the math. ) These are not the types of problems that can be done in the head with intuition. I have learned by bitter experience not to do that.

The desire to locate the electron suggest that one has not yet internalized the situation. There is no more to learn.

A photon is a quanta of energy. A quanta means it is the smallest amount and can not be divided further. This energy is real and equal to Planck’s constant times the frequency of the photon. Photon also carry momentum. They are real things! Mass-less does not mean imaginary. If I put a black object in space motionless relative to my point of observation and it is hit by a photon. The object will absorb the photon and gain the momentum of that photon. This can be measured. Moreover, if I change the object to a mirror the photon will be reflected. In this case conservation of momentum shows that twice the momentum of the photon will be transferred to the mirror. This can be measured and compared to the previous case.

This thought experiment shows that photons are actually real things. Additionally if you go stand outside in sunlight you can convince yourself that the things hitting you are not imaginary.

Black holes do not reach out and swallow light. It is the case that if a photon is inside of the event horizon it can not get out.

--------------------
Michael

ATM: 6" F/9 Newtonian Travel Scope
ATM: 12.5" F/4.5 Real Soon Now...


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Pess
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Reged: 09/12/07
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Re: What drives an atom? new [Re: Joad]
      #2526456 - 07/18/08 12:21 PM

Quote:



.....the Heisenberg Uncertainty Principle, or the Bohr's Copenhagen Interpretation, the position of an electron cannot be measured or observed because the measuring or observing instrument gets in the way....





Actually, the Heisenberg Uncertainty Principle has nothing to do with the measuring apparatus, instead it is a function of quantum probability theory.

Remember when you measure a particle at the quantum level you are 'collapsing' its probability cloud.

There are basically two probabilities involved. One is the momentum possessed by the particle and other is the position of the particle.

In order to measure a given particle you must interact with it. This interaction collapses the probability cloud and alters it from its original parameters. ie: you 'stopping' an electron to pinpoint its position also alters its momentum and vise versa. You can know one property with certainty but not the other.

In fact the function describing this says that the more precise you measure one attribute, the more uncertain you are in regards to the second attribute.

Pesse (I'm pretty certain about the uncertainty.) Mist

--------------------
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Taqyon
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Reged: 06/17/08
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Re: What drives an atom? new [Re: HiggsBoson]
      #2527858 - 07/19/08 06:19 AM

Quote:

Photon also carry momentum.


Hold on - momentum is a function of mass...
Quote:

Black holes do not reach out and swallow light. It is the case that if a photon is inside of the event horizon it can not get out.


I see it as the wave of energy that travels within the fabric of space, is warped along with the fabric into the gravitational pit.

Any other proof that photos are physical particals and not wave energy?

--------------------
Hein du Plessis
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Dane B
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Reged: 02/23/08
Posts: 120
Loc: Seattle, Wa
Re: What drives an atom? new [Re: Taqyon]
      #2527939 - 07/19/08 08:01 AM

Photons as physical particles and not waves: see the photoelectric effect.

Michael - it still doesn't sound kosher to me. As I understand the uncertainty principle, as long as nothing is known about the velocity there should not be a limit to how precisely the location can be known. Why is that not true in the case of an electron in an orbital, be it 1s or otherwise?

--------------------
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Without judgement what would we do? We would be forced to look at ourselves...

-Death


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