ummm, so I have some questions about this. My understanding is that dark current (in each pixel) ramps up linearly with time, and then on top of that there is the sqrt(N) noise. And your chart shows that things level off after about 1 hour of use. Fixed pattern noise means that the signal will be the same even if you took a 1/1000th second exposure(?). So I don't understand because if you subtract one frame from the next after things have "leveled off", that should remove both the fixed pattern noise and also the linearly ramping dark current, leaving only the sqrt(N) part. Are you actually plotting the RMS value of this sqrt(N)?
Next question: Sooo, what are we supposed to do in the first hour worth of picture taking while the Z6 is still heating up?
Yes, dark current accumulates linearly during the exposure time. The fixed pattern noise (FPN) in this case is technically known as the dark current non-uniformity (DCNU) i.e. the fact that some pixels have persistently higher dark current than others leading to brighter pixels in the dark exposure. The dark current is then the standard deviation in the difference frame, squared, divided by 2, divided by the exposure time.
During an imaging session, the light frames taken while the camera is warming up can still be calibrated if you use dark scaling (aka dark optimisation). Typically though, the camera is actually cooling down for for first few exposures because live view has heated it up during framing and focusing.
Mark