There is so much to address in your original post that I really don't know where to begin.
What I should start with is that all the advice you received thus far is spot on. About tracking for imaging the sun... it is not at all necessary. Does tracking make things a bit easier if you fully understand your mount? Absolutely. More often than not, I am doing my solar imaging on one of my manual mounts simply because it is faster and easier to setup. So, honestly tracking isn't necessary for imaging the sun although you can then only slow the shutter speed so much if imaging the corona before you start getting motion blurring.
For the corona, however, I'd really recommend a camera in hand or on a photographic tripod, no filter, so you can change settings very quickly. It is hard to change settings quickly if the camera is hanging off the back of a telescope... been there, done that, and it is no fun. There isn't much time and you need a lot of different exposures in this short amount of time so quick access is required. You settings for images/video during partial phases with a filter will be totally different than without a filter during totality. Additionally, for the corona, you'll really only want to be at around 400mm (full frame equivalent) to capture both the sun/moon and most of the corona.
About the iEXOS100...
First, the PMC8 mounts are open source so they are slightly different than most mounts. Keep that in mind. There is a bit of a learning curve especially if you are used to the mainstream mounts.
Actually, it is too late now but the Skywatcher SolarQuest mount would have been the ideal mount for the eclipse with no time to learn new things. That mount requires you to level the tripod and then turn it on. It does the rest by itself and GPS satellites. The downside is it is a Solar-only mount. You don't have that though so let me try to explain a few of the unusual things about the PMC8 mounts.
These mounts can be controlled via WiFi or serial connection to a computer. WiFi is only useful if you are using the ExploreStars app. If you plan to use any other program(s) that send commands to the mount, then you must connect via serial USB.
There will be a new version of the ExploreStars app that can be used on cellphones but it has not been released yet. For now, the interface is designed for larger tablets as well as laptops and desktops. It has a lot of photos of the targets in the sky so having the extra larger size is welcomed. There is quite a bit of useful info on the main screen at once. The device must have 2.4GHz WiFi to connect to the mount. This wireless app is ideal for visual use although I admit that I do also use ExploreStars for solar imaging. Select the sun, GoTo, then center it, and it tracks.
Next, if you plan to use multiple pieces of software that each must connect to the mount, then you must be in serial mode connected to a laptop or desktop. You also should have already downloaded and installed the PMC8 driver on your device. The mount can only connect and get commands from one piece of software so you must use ASCOM Device Hub or ASCOM POTH as a hub that connects to multiple programs and simultaneously sends the mount commands. Device Hub is the most recent hub and that is what I recommend.
I'm going to write by memory here so this may not be perfect but it will get you closer to where you want to be. You set up the mount and connect to your laptop using the appropriate USB cable. For the iEXOS100, it is a simply cable with no FTDI chip. The necessary chips are already inside the mount. Power up the mount.
You open Device Hub and connect to the mount by selecting the PMC8 driver in the drop-down menu (choosing a telescope). Make sure you set up all the tabs in the driver properly for your site and make sure you have the iEXOS100 selected. This driver is for ALL the PMC8 mounts and each is different so you need to make sure you have selected the iEXOS100.
Now, for each piece of software that wants to connect to the mount, you DO NOT select the iEXOS100 in the piece of software. You select ASCOM/Device Hub. The programs will talk to Device Hub and then Device Hub will sort it all out in real time and send the proper commands to the mount.
Since you are short on time at this point, I don't recommend checking and updating the firmware of the mount unless you encounter some sort of problem this week. You really don't need that extra complication right now with time so tight. There is a whole other learning curve in using the utility for checking and updating the firmware. It is easy and works well but, like anything else new, it takes some time to crawl before you can walk. When you get to this point, you can find the most recent firmware package on the Explore Scientific website listed under the "Mounts" menu ---> "Software and Downloads".
For what it's worth and to put the info our there for anyone else reading this thread, much of this PMC8 software, firmware and driver has been written by volunteers and they have done an outstanding job.
For the solar eclipse, keep things as simple as possible especially when using new equipment.
I think I covered everything to get you started. Good luck and enjoy the eclipse!
Patrick