XRF analysis is a good idea, but since the amount of nickel can vary only by a couple of percentage points between types, it may not prove to be definitive. It is of course invaluable in determining meteoritic vs terrestrial origin.
A simple test can reveal the type of iron though, Gibeon, being a fine octahedrite has a distinctive Widmanstatten pattern which can not be mistaken for a Canyon Diablo which is a coarse octahedrite.
Simply remove the patina in a small relatively smooth area, 3/4 of an inch across is sufficient, ending with 400 - 600 grit sanding. Apply a dilute solution of nitric acid (easily found, it's commonly used in testing precious metals). If the pattern looks like the one in the image below, it is a fine octahedrite and quite possibly Gibeon. Canyon Diablo is a coarse octahedrite, and although the etched appearance varies widely between specimens, none of them can be confused with a fine octahedrite.
The specimen below was tested by the method described above to confirm its identity when I purchase it twenty years ago. It's not a perfect etch, the contrast is low, but it is adequate to confirm the specimen as a fine octahedrite.
Lee