As a machinist myself I think this would be a risky business. I believe the spiders on these telescopes are castings and if so might not have the structural integrity necessary if thinned. A better approach would be to replace the vanes with a thinner but brass or steel material. I doubt that you would see much difference though as the large secondary accounts for most of the obstruction effect.
I am with Peter on this. I'm a retired mechanical engineer who worked closely with a number of excellent machinists.. One of the keys to my success as an engineer was always listening to the machinist, I would discuss the designs with them prior to making the actual drawings and then once the drawing was done, I would discuss it with them again.
As a mechanical engineer, I see two problems.. The vanes are cast which makes them brittle, they could easily fracture under the vibration and side loading from the mill. Second, they are not under tension. What makes thin vanes possible is the fact that they are tensioned.
If you are going to try to thin the vanes, I agree with "notdarkenough", replace the case vanes with tensioned steel vanes. This could be done by hand with a minimum of tools. I could even do it.
I would not recommend 3-D printing for a number of reasons.
Jon