I spent many months working in Bolivia while I was living in Argentina, my birth country.
The sky is just amazing, hard to describe in words.
The only negative point was altitude and its side effects.
#1 Temperature. It's very cold, summer noon is 10C / 50F, and nights fall below -10C / 14F.
#2 Dryness. Bring some cream to protect your skin from a 15%-25% humidity environment.
#3 UV. Sunscreen is a must, unless you plan to sleep during daytime and observe all night (not a bad idea)
#4 Altitude sickness. I had strong headaches and nausea for the first 2-3 days.
Locals may offer you coca tea or to chew raw coca leaves, accept them. Helps a lot with "apunamiento" (altitude sickness).
Move slowly, don't run. You will feel exhausted after a few seconds.
It's true there's a lot of dust floating around, but it's still a great place for observation.
If you're unsure about altitude, go to lower sites like Cochabamba, Sucre or Samaipata.
Sucre is at 2800 m (9000 ft), Cochabamba at 2500m (8000 ft) and Samaipata at 1700 m (5000 ft).
Samaipata is warmer and more humid (sadly, there are some mosquitoes).
Of course, don't observe from the cities themselves, just drive 1-2 hours and you'll be under amazing skies.
Socially speaking, I wouldn't qualify the Bolivian Andes as a dangerous place.
Mountains isolation and harsh conditions are dangerous, not the locals themselves.
Bolivians are friendly and respectful as long as you don't rush them.
Go with the flow, don't lose your temper and good manners.
Transportation is precarious, don't be surprised if your local plane or bus are delayed 24 hours.
So, don't visit the area under a tight schedule, keep a couple of "buffer" days for unexpected delays.
Obviously, medium-level Spanish skills help.
If you don't speak Spanish, just bring your cell with Google Translator and download the offline Spanish dictionary.