I have both, they both offer certain advantages.
i got the Nexus first. It takes a little work to rig up attachments for the encoders, but once set up they're extremely accurate and easy to use.
The PiFinder is easy to set up, and it works great, but it's a bit of a continuing approximation of where you're pointing as you get closer and closer to your object, while with the Nexus it's just fast and rock solid as to exactly where the scope is pointed.
The big advantage for me with the Pifinder is that I do most of my observing portable, setting up and breaking down my scopes over and over as I'm traveling. The encoders for the Nexus make that process a bit more complicated, it just gets to be a hassle. If I just observed at home I'd probably stick with the Nexus, but for portable use the Pifinder is a lot more convenient.
Another option is the Cedar. I also built one of those too since it's so much cheaper and easier to do. A simplified version of the Pifinder where your smartphone or tablet is the display, and it doesn't have the GPS or accelarometers that the Pifinder has. On the other hand it was about one fourth the price and does about 90 percent as well. If you're just curious about the idea I can highly recommend the Cedar setup, it's just a Pi with a camera in a 3D printed housing, so just a little over $100 up and running. There's a thread on this site about them but I think it's in the vendor section for it's a little hard to find without searching.